213934

Bis(triphenylphosphine)dicarbonylnickel

solid

• Synonym(s): Bis(triphenylphosphine)nickel(0)dicarbonyl, Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl
• Linear Formula: [(C₆H₅)₃P]₂Ni(CO)₂
• CAS Number: 13007-90-4
• Molecular Weight: 639.28
• NACRES: NA.22
• PubChem Substance ID: 24852811
• UNSPSC Code: 12161600
• EC Number: 235-851-9
• MDL number: MFCD00009591

Properties

• Product Name: Bis(triphenylphosphine)dicarbonylnickel,
• form: solid
• Quality Level: 100
• reaction suitability: core: nickel, reagent type: catalyst
• mp: 206-209 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [Ni].[C-]#[O+].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2CO.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;/h2*1-15H;;;
• InChI key: SLFKPACCQUVAPG-UHFFFAOYSA-N

Description

Application

Catalyst for:

• Cyclotrimerization reactions
• Cyclooligomerization reactions

Safety Information

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H317,H350
• pcodes: P201 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Carc. 1B - Skin Sens. 1
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges