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Quality Level
Assay
97%
optical activity
[α]20/D −8°, c = 1 in chloroform
mp
65-69 °C (lit.)
functional group
amine
hydroxyl
SMILES string
CC(C)(C)OC(=O)N[C@H](CO)CCO
InChI
1S/C9H19NO4/c1-9(2,3)14-8(13)10-7(6-12)4-5-11/h7,11-12H,4-6H2,1-3H3,(H,10,13)/t7-/m0/s1
InChI key
KLRRFBSWOIUAHZ-ZETCQYMHSA-N
Application
(S)-(−)-2-(Boc-amino)-1,4-butanediol can be used as a reactant to synthesize:
- Thiourea-based organocatalysts for asymmetric Michael addition reactions of nitroalkenes to α-nitrocyclohexanone.
- Bis-copper (II) complex based catalysts for enantioselective Michael reactions.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Copper (II) in organic synthesis. XI. Evaluation of the ligand architecture on the efficiency of a copper (II) catalyst for enantioselective Michael reactions
Tetrahedron, 51(14), 4131-4144 (1995)
Asymmetric Michael additions of α-nitrocyclohexanone to aryl nitroalkenes catalyzed by natural amino acid-derived bifunctional thioureas
Organic Letters, 14(17), 4518-4521 (2012)
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