419532

2-Methylallylmagnesium chloride solution

0.5 M in THF

• Synonym(s): (2-Methyl-2-propenyl)magnesium chloride, Chloro(2-methyl-2-propenyl)magnesium, Chloro(2-methylallyl)magnesium, Methallylmagnesium chloride
• Linear Formula: H₂C=C(CH₃)CH₂MgCl
• CAS Number: 5674-01-1
• Molecular Weight: 114.86
• MDL number: MFCD00674003
• UNSPSC Code: 12352103
• PubChem Substance ID: 24866258
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• Quality Level: 100
• concentration: 0.5 M in THF
• bp: 65-67 °C
• density: 0.915 g/mL at 25 °C
• SMILES string: CC(=C)C[Mg]Cl
• InChI: 1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1
• InChI key: BJVFGWYBOLMUEM-UHFFFAOYSA-M

Description

Application

2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H261,H302,H314,H335,H351
• Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): -5.8 °F - closed cup
• Flash Point(C): -21 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves