290998
Pentylmagnesium bromide solution
2.0 M in diethyl ether
Synonym(s):
1-Pentylmagnesium bromide, n-Pentylmagnesium bromide, Amylmagnesium bromide, Bromopentylmagnesium
About This Item
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in diethyl ether
density
0.947 g/mL at 25 °C
SMILES string
CCCCC[Mg]Br
InChI
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI key
ZXWGTPYWPZGZPT-UHFFFAOYSA-M
Application
- Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
- Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
-40.0 °F - closed cup
Flash Point(C)
-40 °C - closed cup
Personal Protective Equipment
Certificates of Analysis (COA)
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