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Sigma-Aldrich

Tris(2-aminoethyl)amine

96%

Synonym(s):

2,2′,2′′-Nitrilotriethylamine, 2,2′,2′′-Triaminotriethylamine, TAEA

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About This Item

Linear Formula:
(NH2CH2CH2)3N
CAS Number:
4097-89-6
Molecular Weight:
146.23
Beilstein:
1739626
EC Number:
223-857-4
MDL number:
MFCD00008177
UNSPSC Code:
12162002
PubChem Substance ID:
24853509
NACRES:
NA.23

vapor density

5 (vs air)

vapor pressure

0.02 mmHg ( 20 °C)

Assay

96%

form

liquid

refractive index

n20/D 1.497 (lit.)

bp

114 °C/15 mmHg (lit.)

density

0.976 g/mL at 20 °C (lit.)

SMILES string

NCCN(CCN)CCN

InChI

1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2

InChI key

MBYLVOKEDDQJDY-UHFFFAOYSA-N

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General description

Tris(2-aminoethyl)amine (TREN) is a water soluble tripodal ligand that is majorly used in co-ordination chemistry. It has three aminoethylgroups that attach with the surface atoms to provide a scaffold assembly.

Application

Building block for cryptands; precursor to a proazaphosphatrane, a stong, nonionic base.
TREN can be grafted with multi-walled carbon nanotube (MWCNT) for use in solid phase extraction of metal ions for wastewater treatment based applications. It can also be used as a chelating agent in the surface treatment of silica nanoparticles which can further be used for a wide range of industrial applications.

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301,H310,H314

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Skin Corr. 1B

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Removal of lead ions from wastewater using functionalized multiwalled carbon nanotubes with tris (2-aminoethyl) amine
Tehrani MS, et al.
Journal of Environmental Protection, 4(06), 529-529 (2013)
Polish Journal of Chemistry, 80, 1825-1825 (2006)
Surface treatment of silica nanoparticles for stable and charge-controlled colloidal silica
Kim K, et al.
International journal of nanomedicine, 9(2), 29-29 (2014)
Living radical polymerization of vinyl chloride initiated with iodoform and catalyzed by nascent Cu0/tris (2-aminoethyl) amine or polyethyleneimine in water at 25? C proceeds by a new competing pathways mechanism.
Percec V, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 41(21), 3283-3299 (2003)
Jung-Ho Shin et al.
Proceedings of the National Academy of Sciences of the United States of America, 108(12), 5045-5050 (2011-03-09)
Zinc is one of the essential transition metals in cells. Excess or lack of zinc is detrimental, and cells exploit highly sensitive zinc-binding regulators to achieve homeostasis. In this article, we present a crystal structure of active Zur from Streptomyces
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