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168521

Sigma-Aldrich

Luperox® DI, tert-Butyl peroxide

98%

Synonym(s):

tert-Butyl peroxide, Di-tert-butyl peroxide

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About This Item

Linear Formula:
(CH3)3COOC(CH3)3
CAS Number:
110-05-4
Molecular Weight:
146.23
Beilstein:
1735581
EC Number:
203-733-6
MDL number:
MFCD00008803
UNSPSC Code:
12352120
PubChem Substance ID:
24850244
NACRES:
NA.22

vapor pressure

40 mmHg ( 20 °C)

Assay

98%

form

liquid

reaction suitability

reagent type: oxidant

refractive index

n20/D 1.3891 (lit.)

bp

109-110 °C (lit.)

density

0.796 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)(C)OOC(C)(C)C

InChI

1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3

InChI key

LSXWFXONGKSEMY-UHFFFAOYSA-N

Application

Luperox®DI, tert-Butyl peroxide has been used as a radical initiator to induce free radical polymerization. It has also been used as a cetane enhancer in a study to determine the phase behavior of carboxylate-based extended surfactant reverse micellar microemulsions with ethanol and vegetable oil/diesel blends.

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Pictograms

FlameHealth hazard
GHS02,GHS08

Signal Word

Danger

Hazard Statements

H225,H242,H341,H412

Hazard Classifications

Aquatic Chronic 3 - Flam. Liq. 2 - Muta. 2 - Org. Perox. E

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flash Point(F)

42.8 °F - closed cup

Flash Point(C)

6 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A Mortensen et al.
FEBS letters, 426(3), 392-396 (1998-05-26)
Peroxyl radicals, as model for peroxyl radicals formed during autoxidation of lipids, have been generated in three solvent systems (cyclohexane, tetrahydrofuran and tert-butanol/water) by steady-state and laser flash photolysis, and their reaction with beta-carotene studied. Steady-state photolysis experiments showed that
Carson T Riche et al.
Nature communications, 7, 10780-10780 (2016-02-24)
The translation of batch chemistries onto continuous flow platforms requires addressing the issues of consistent fluidic behaviour, channel fouling and high-throughput processing. Droplet microfluidic technologies reduce channel fouling and provide an improved level of control over heat and mass transfer
Hironori Kitaguchi et al.
Journal of the American Chemical Society, 127(18), 6605-6609 (2005-05-05)
Well-resolved ESR spectra of free pentadienyl radicals have been observed under photoirradiation of di-tert-butylperoxide (Bu(t)OOBu(t)) and polyunsaturated fatty acids in the absence of O(2), allowing us to determine the hfc values. The hfc values of linoleyl radical indicate that the
Free radical polymerization of caffeine?containing methacrylate monomers.
Nelson AM
Journal of Polymer Science Part A: Polymer Chemistry, 53(24), 2829-2837 (2015)
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