B4007
1,2,4,5-Benzenetetracarboxylic acid
96%
Synonym(s):
Pyromellitic acid
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All Photos(3)
About This Item
Linear Formula:
C6H2(CO2H)4
CAS Number:
Molecular Weight:
254.15
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
96%
form
powder
mp
281-284.5 °C (lit.)
SMILES string
OC(=O)c1cc(C(O)=O)c(cc1C(O)=O)C(O)=O
InChI
1S/C10H6O8/c11-7(12)3-1-4(8(13)14)6(10(17)18)2-5(3)9(15)16/h1-2H,(H,11,12)(H,13,14)(H,15,16)(H,17,18)
InChI key
CYIDZMCFTVVTJO-UHFFFAOYSA-N
Related Categories
Application
1,2,4,5-Benzenetetracarboxylic acid is extensively used as a ligand in the synthesis of a wide range of metal-organic frameworks (MOFs) and coordination polymers. It can also be used to prepare supramolecular hydrogels by synthesizing gelators reacting 1,2,4,5-benzenetetracarboxylic acid with 4-hydroxy pyridine.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
617.0 °F
Flash Point(C)
325 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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A Chattopadhyay et al.
Journal of chromatography. A, 758(2), 255-261 (1997-01-17)
A capillary electrophoresis (CE) method was developed for determining the diol content of supports used in high-performance affinity or size exclusion chromatography. This method involved oxidizing the diol-bonded support with periodate, followed by the use of CE to separate and
James E A Webb et al.
Journal of the American Chemical Society, 129(22), 7155-7162 (2007-05-15)
The N,N',N'',N'''-1,2,4,5-tetra(ethylhexanoate) pyromellitamide is found to be capable of both intermolecular aggregation and binding to small anions. It is synthesized by aminolysis of pyromellitic anhydride with ethanolamine, followed by a reaction with hexanoyl chloride. The single-crystal X-ray structure of the
Yauhen Y Karabach et al.
Journal of inorganic biochemistry, 102(5-6), 1190-1194 (2008-01-08)
The new inorganic 1D coordination polymer [Cu2(H3tea)2(mu4-pma)]n has been prepared, via self-assembly in aqueous medium, from copper(II) nitrate, triethanolamine (H3tea), pyromellitic acid (H4pma) and lithium hydroxide, and characterized by IR spectroscopy, elemental and single-crystal X-ray diffraction analyses. This compound and
Gustavo A Blanco-Heras et al.
Journal of chromatography. A, 1144(2), 275-278 (2007-02-13)
Selectivity and robustness of the pyromellitic acid (PMA) based background electrolyte was improved in order to increase its applicability for routine analysis of inorganic and organic anions in real samples. An electrolyte composed of 6.75 mM PMA, 0.5 mM hexamethonium
1, 2, 4, 5?Benzenetetracarboxylic Acid and 4, 4??Bipyridine as Ligands in Designing Low?Dimensional Coordination Polymers.
Ruiz?Perez C, et al.
European Journal of Inorganic Chemistry, 2004(19), 3873-3879 (2004)
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