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156388

Sigma-Aldrich

Pentafluorophenylhydrazine

97%

Synonym(s):

(Perfluorophenyl)hydrazine, NSC 88334, PFPH

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About This Item

Linear Formula:
C6F5NHNH2
CAS Number:
828-73-9
Molecular Weight:
198.09
Beilstein:
747800
EC Number:
212-586-7
MDL number:
MFCD00007574
UNSPSC Code:
12352100
PubChem Substance ID:
24849610
NACRES:
NA.22

Quality Level

100

Assay

97%

form

powder

mp

74-76 °C (lit.)

SMILES string

NNc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C6H3F5N2/c7-1-2(8)4(10)6(13-12)5(11)3(1)9/h13H,12H2

InChI key

BYCUWCJUPSUFBX-UHFFFAOYSA-N

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Application

The product has been used to determine the purity of N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl)]nitroxide (DEPN) using 1H NMR spectroscopy.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Xiaobing Pang et al.
The Science of the total environment, 409(23), 5000-5009 (2011-09-20)
Carbonyl compounds (carbonyls) are important constituents of cigarette smoke and some are toxic and may be carcinogenic or mutagenic to humans. In this study carbonyl emissions in the gas and particle phases of mainstream cigarette smoke were assessed by GC-MS
E E Stashenko et al.
Journal of chromatography. A, 779(1-2), 360-369 (1997-08-29)
High-resolution gas chromatography (HRGC) with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), flame ionization detection (FID) or with mass spectrometry-selected ion monitoring (MS-SIM) was used in the analysis of volatile carbonyl compounds. Eighteen carbonyl compounds that are typically produced during lipid
Rene Thomas Rivero et al.
Journal of cosmetic science, 55(4), 343-350 (2004-09-24)
The objective of this research was the application of headspace (HS)-solid-phase microextraction (SPME) for the quantitation of formaldehyde present in raw materials and cosmetic formulations. The formaldehyde was derivatized in situ first with pentafluorophenylhydrazine (PFPH), to form a derivative hydrazone.
Michael Otteneder et al.
Chemical research in toxicology, 15(3), 312-318 (2002-03-19)
Malondialdehyde is a ubiquitous product of lipid peroxidation that reacts with DNA to form premutagenic lesions. Principal among them is pyrimido-[1,2-alpha]purin-10(3H)-one (M(1)G). M(1)G has recently been found to be a reactive electrophile in DNA that couples with amines at basic
Elena E Stashenko et al.
Journal of chromatographic science, 44(6), 347-353 (2006-08-04)
Specific chromatographic methodologies are developed for the analysis of carboxylic acids (C(2)-C(6), benzoic) and aldehydes (C(2)-C(10)) of low molecular weight in diverse matrices, such as air, automotive exhaust gases, human breath, and aqueous matrices. For carboxylic acids, the method is
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