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Sigma-Aldrich

1,2-Cyclohexanedicarboxylic anhydride, predominantly cis

95%

Synonym(s):

Hexahydrophthalic anhydride

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About This Item

Empirical Formula (Hill Notation):
C8H10O3
CAS Number:
Molecular Weight:
154.16
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

95%

form

solid

bp

158 °C/17 mmHg (lit.)

mp

32-34 °C (lit.)

SMILES string

O=C1OC(=O)[C@H]2CCCC[C@@H]12

InChI

1S/C8H10O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h5-6H,1-4H2/t5-,6+

InChI key

MUTGBJKUEZFXGO-OLQVQODUSA-N

General description

Predominantly cis 1,2-cyclohexanedicarboxylic anhydride (HHPA) is a cyclic anhydride that can be used for a variety of applications such as: plasticizer, rust inhibitor, and a curing agent for epoxy based resins.

Application

HPPA, in combination with triethaylamine (TEA), can be used as a polymerization initiator in the preparation of polyester based resins. It can also be used as a hardener to cure 1,4-butanediol diglycidyl ether which can be used as an epoxy based system for electronic devices.

Pictograms

Health hazardCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Monica H Kristiansson et al.
Rapid communications in mass spectrometry : RCM, 18(14), 1592-1598 (2004-07-30)
Organic acid anhydrides (OAAs) are low molecular weight, reactive compounds extensively used in industry. Exposure to these compounds may lead to allergic symptoms such as rhinitis and asthma. It is important to develop better and more informative methods for assessment
David Virley et al.
Journal of cerebral blood flow and metabolism : official journal of the International Society of Cerebral Blood Flow and Metabolism, 24(1), 24-41 (2003-12-23)
The purpose of the present set of studies was to develop a new primate model of focal ischemia with reperfusion for long-term functional assessment in the common marmoset. Initially, the cerebral vascular anatomy of the marmoset was interrogated by Araldite-cast
J Nielsen et al.
Scandinavian journal of work, environment & health, 27(5), 327-334 (2001-11-20)
This study clarified the exposure-response relationships for the organic acid anhydrides (OAA) hexahydrophthalic (HHPA) and methylhexahydrophthalic (MHHPA) anhydrides and the development of specific immunoglobulin (IG) E and G antibodies and work-related symptoms. In an epoxy resin-using factory, air levels of
Isla Mickey et al.
The Histochemical journal, 34(10), 469-477 (2003-08-30)
In this study, we show the changes in the wall of the middle cerebral artery of a subject who suffered multiple system atrophy with autonomic failure. An electron-immunocytochemical approach was employed to reveal the presence of endothelin-1. Our results demonstrate
Bénédicte Le Crom et al.
The Journal of the Acoustical Society of America, 127(4), 2220-2230 (2010-04-08)
This paper presents a non-destructive, ultrasonic technique to evaluate the quality of bonds between substrates. Shear-horizontally polarized (SH) wave modes are investigated to infer the shear stiffness of bonds, which is necessarily linked to the shear resistance that is a

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