Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
434280
Boron trifluoride tetrahydrofuran complex
contains >0.5% sulfur dioxide as peroxide formation suppressor
Synonym(s):
BF3·THF, Boron trifluoride THF complex
About This Item
Recommended Products
form
liquid
contains
>0.5% sulfur dioxide as peroxide formation suppressor
reaction suitability
core: boron
reagent type: Lewis acid
reagent type: catalyst
bp
180 °C (lit.)
mp
11-13 °C (lit.)
density
1.268 g/mL at 25 °C (lit.)
functional group
ether
SMILES string
FB(F)F.C1CCOC1
InChI
1S/C4H8BF3O/c6-5(7,8)9-3-1-2-4-9/h1-4H2
InChI key
XYMZNNGTHKHCJH-UHFFFAOYSA-N
Application
- Deoxofluorination of alcohols and carbonyls
- Synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes
- Hydroboration-oxidation of divinylferrocene
Reagent involved in the synthesis of biologically active molecules such as:
- NK1 receptor antagonists
- Complex polyketide natural products
- Selective serotonin reuptake inhibitors
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1 Inhalation
Target Organs
Kidney
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
Flash Point(F)
189.5 °F - closed cup
Flash Point(C)
87.5 °C - closed cup
Personal Protective Equipment
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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