673307

Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate

solid

• Synonym(s): (Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate, Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
• Linear Formula: [(C₅H₅)Ru(CH₃CN)₃]PF₆
• CAS Number: 80049-61-2
• Molecular Weight: 434.28
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760546
• NACRES: NA.22
• MDL number: MFCD02684569

Properties

• Product Name: Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate,
• form: solid
• Quality Segment: 100
• reaction suitability: core: ruthenium, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• greener alternative category: Aligned
• storage temp.: 2-8°C
• SMILES string: [Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
• InChI: 1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
• InChI key: HJQVFVSAQOQXRG-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Catalyst for:

• Regioselective and stereoselective dehydrative allylation of nucleophiles
• O-H Insertion and condensation reactions
• Hydrosilylation
• Decarboxylative allylic etherification
• Claisen rearrangement of unactivated allyl vinyl ethers

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves