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383066

Sigma-Aldrich

Lead(II) perchlorate trihydrate

ACS reagent, 98%

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About This Item

Linear Formula:
Pb(ClO4)2·3H2O
CAS Number:
Molecular Weight:
460.15
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

Quality Level

Assay

97.0-102.0% (ACS specification)
98%

form

crystals

reaction suitability

reagent type: oxidant

impurities

≤0.005% insolubles

pH

3.0-5.0 (25 °C, 5%)

anion traces

chloride (Cl-): ≤0.01%

cation traces

Fe: ≤0.001%

SMILES string

O.O.O.[PbH2++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.3H2O.Pb/c2*2-1(3,4)5;;;;/h2*(H,2,3,4,5);3*1H2;/q;;;;;+2/p-2

InChI key

KKGGEAQRICYXNM-UHFFFAOYSA-L

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General description

Lead(II) perchlorate trihydrate is a perchlorate compound. It leads to protonation of the pyridyl group on interaction with pyridyldithiafulvene ligands.

Application

Lead(II) perchlorate trihydrate may be used in the synthesis of calix[4]arene thioamides and macrocyclic lead(II) complexes.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Ox. Sol. 2 - Repr. 1A - STOT RE 2

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Pyridyldithiafulvene as N-ligand towards molybdenum carbonyl complexes and evidence of protonation through hydrolysis of lead perchlorate.
Guerro M, et al.
Journal of Organometallic Chemistry, 696(7), 1367-1371 (2011)
Preparation and Crystal Structures of Silver (I), Mercury (II), and Lead (II) Complexes of Oxathia-Tribenzo-Macrocycles.
Siewe AD, et al.
Bull. Korean Chem. Soc., 34(3), 725-725 (2013)
Lower rim substituted p-tert-butyl calix [4] arene; Part 14. Synthesis, structures and binding studies of calix [4] arene thioamides.
Bochenska M, et al.
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 68(1-2), 75-83 (2010)

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