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54913

Sigma-Aldrich

Lithium β-hydroxypyruvate hydrate

≥97.0% (calc. based on dry substance, NT)

Synonym(s):

β-Hydroxypyruvic acid lithium salt hydrate, 3-Hydroxy-2-oxopropanoic acid lithium salt, 3-Hydroxy-2-oxopropionic acid lithium salt

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About This Item

Linear Formula:
HOCH2COCOOLi · aq
CAS Number:
3369-79-7
Molecular Weight:
109.99 (anhydrous basis)
Beilstein:
5774840
MDL number:
MFCD10567214
UNSPSC Code:
12352100
PubChem Substance ID:
57651487
NACRES:
NA.22

Assay

≥97.0% (calc. based on dry substance, NT)

impurities

~1 mol water

SMILES string

[Li+].O.OCC(=O)C([O-])=O

InChI

1S/C3H4O4.Li.H2O/c4-1-2(5)3(6)7;;/h4H,1H2,(H,6,7);;1H2/q;+1;/p-1

InChI key

YHTVWBANKNBEKJ-UHFFFAOYSA-M

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Application

  • Chiral polyol synthesis catalyzed by a thermostable Transketolase immobilized on Layered Double Hydroxides in Ionic liquids: Examines the catalytic applications of lithium β-hydroxypyruvate in chiral synthesis processes (Ali et al., 2015).

Other Notes

Substrate for transketolase; Preparation of optically pure L-2-hydroxy aldehydes

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Shweta Joshi et al.
Molecular and biochemical parasitology, 160(1), 32-41 (2008-05-06)
The pentose phosphate pathway (PPP) is an important metabolic pathway for yielding reducing power in the form of NADPH and production of pentose sugar needed for nucleic acid synthesis. Transketolase, the key enzyme of non-oxidative arm of PPP, plays a
O N Solov'eva et al.
Biochemistry. Biokhimiia, 66(8), 932-936 (2001-09-22)
The interaction of transketolase ketosubstrates with the holoenzyme has been studied. On addition of ketosubstrates cleaving both irreversibly (hydroxypyruvate) and reversibly (xylulose 5-phosphate), identical changes in the CD spectrum at 300-360 nm are observed. The changes in this spectral region
Silke C Wenzel et al.
Journal of the American Chemical Society, 128(44), 14325-14336 (2006-11-02)
Feeding experiments with isotope-labeled precursors rule out hydroxypyruvate and TCA cycle intermediates as the metabolic source of methoxymalonyl-ACP, the substrate for incorporation of "glycolate" units into ansamitocin P-3, soraphen A, and other antibiotics. They point to 1,3-bisphosphoglycerate as the source
F. Effenberger et al.
Tetrahedron Letters, 33, 5157-5157 (1992)
Seong Pil Chung et al.
Journal of biochemistry, 148(6), 743-753 (2010-09-30)
D-amino acid oxidase (DAO) is a flavoenzyme that exists in the kidney, liver and brain of mammals. This enzyme catalyzes the oxidation of D-amino acids to the corresponding α-keto acid, hydrogen peroxide and ammonia. Recently D-serine, one of the substrates
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