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491047

Sigma-Aldrich

2-(Bromomethyl)pyridine hydrobromide

98%

Synonym(s):

(2-Pyridyl)methyl bromide hydrobromide, 2-Bromomethylpyridine monohydrobromide, 2-Picolyl bromide-hydrobromide

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About This Item

Empirical Formula (Hill Notation):
C6H6BrN · HBr
CAS Number:
31106-82-8
Molecular Weight:
252.93
MDL number:
MFCD01863544
UNSPSC Code:
12352100
PubChem Substance ID:
24872629
NACRES:
NA.22

Quality Level

100

Assay

98%

mp

149-152 °C (lit.)

functional group

bromo

SMILES string

Br[H].BrCc1ccccn1

InChI

1S/C6H6BrN.BrH/c7-5-6-3-1-2-4-8-6;/h1-4H,5H2;1H

InChI key

JQDNCGRNPYKRAO-UHFFFAOYSA-N

Related Categories

General description

2-(Bromomethyl)pyridine hydrobromide is a pyridine derivative. It participates in the synthesis of 7-nitrobenz-2-oxa-1,3-diazole (NBD) based colorimetric and fluorescence chemosensor.

Application

2-(Bromomethyl)pyridine hydrobromide may be used in the preparation of :
  • 2-[1-(pyridin-2-ylmethyl)-1H-1,2,3-triazol-4-yl]pyridine
  • 2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • 8-methyl-2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • trans-4-(4-(bis(pyridin-2-ylmethyl)amino)styryl)benzonitrile
  • 2-[N-(2-aminoethanethiol) methyl]-pyridine
  • 2-[N-(ethylenediamino)-methyl]-pyridine
  • 3-(carboxymethyl)-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate
  • 3-[(S)-1-carboxy-2-methylpropyl]-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT0689
MKCJ6763
MKCB2254V
MKBR0169V
MKBL3851V

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Synthesis and characterization of platinum (II) complexes from trifluoromethyl phenylenediamine, picoline and N-benzyl ethylenediamine derivatives.
Almeida MVD, et al.
Journal of the Brazilian Chemical Society, 17(7), 1266-1273 (2006)
An NBD-based colorimetric and fluorescent chemosensor for Zn2+ and its use for detection of intracellular zinc ions.
Xu Z, et al.
Tetrahedron, 65(11), 2307-2312 (2009)
Green Catalysts: Solid-Phase Peptide Carbene Ligands in Aqueous Transition-Metal Catalysis.
Worm-Leonhard K and Meldal M.
European Journal of Organic Chemistry, 2008(31), 5244-5253 (2008)
A stilbene-based fluoroionophore for copper ion sensing in both reduced and oxidized environments.
Zhu MQ, et al.
Talanta, 81(1), 678-683 (2010)
A multicomponent CuAAC ?click? approach to a library of hybrid polydentate 2-pyridyl-1,2,3-triazole ligands: new building blocks for the generation of metallosupramolecular architectures.
Crowley JD and Bandeen PH.
Dalton Transactions, 39(2), 612- 623 (2010)
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