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804975

DTBPF-Pd-G3

solid

Synonym(s):

1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3

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Size/SKUAvailabilityPrice
250 mg
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₪497.00
1 g
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₪1,677.00
5 g
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₪4,613.00

About This Item

Empirical Formula (Hill Notation):
C39H57FeNO3P2PdS
CAS Number:
Molecular Weight:
844.15
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
MDL number:

₪497.00


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Product Name

DTBPF-Pd-G3,

Quality Segment

product line

Buchwald precatalyst Generation 3

form

solid

feature

generation 3

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

impurities

may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156), may contain 5-10% DTBPF (Aldrich Number 695149), may contain 5-10% pentane

mp

87-150 °C (decomposition)

functional group

phosphine

InChI

1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key

AGXLTHQKOWPGBX-UHFFFAOYSA-M

General description

DTBPF-Pd-G-3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF3, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.

Application

Pd precatalyst for cross-coupling. Buchwald Third Generation Palladium Precatalyst.

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This Item
756482792357745979
reaction suitability

core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Heck Reaction, reaction type: Stille Coupling

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

-

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

form

solid

form

solid

form

solid

form

solid

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

87-150 °C (decomposition)

mp

167-170 °C (decomposition)

mp

245-250 °C

mp

119-131 °C

feature

generation 3

feature

generation 2

feature

generation 3

feature

generation 3


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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