Instructions for use of this column are available in the documentation section. The monomer can be added dropwise to the column. For very viscous or high-melting solid monomers, dilution in an appropriate solvent before addition to the column is recommended. As long as the monomer is fully dissolved, there should not be an issue with elution from the column. An additional rinse with solvent can be performed to ensure complete elution.
306312
Inhibitor removers
Prepacked column for removing hydroquinone and monomethyl ether hydroquinone
Synonym(s):
Inhibition Removal Agents
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| Size/SKU | Availability | Price |
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1 ea | Available to ship TODAYfromMILWAUKEE | $120.00 |
12 ea | Available to ship TODAYfromMILWAUKEE | $739.00 |
About This Item
$120.00
Available to ship TODAYDetails
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Ships Every 4 weeks
vapor pressure
17 mmHg ( 20 °C)
Quality Segment
form
beads
column size
17 mm × 240 mm
SMILES string
[Al]21O[Al](O2)O1
InChI
1S/2Al.3O
InChI key
TWNQGVIAIRXVLR-UHFFFAOYSA-N
General description
Inhibitor-remover packings and ready-to-use, disposable prepacked columns conveniently remove small amounts of inhibitors which are added to reagents or solvents that would otherwise be unstable. R: 20-37 S: 22-38-36
• Useful in applications which require that the stabilizer or inhibitor (hydroquinone (HQ), hydro-quinone monomethyl ether (MEHQ, 4-methoxyphenol), or 4-tert-butylcatechol (TBC) be removed prior to use.
• Columns may be discarded1 when exhausted or reused by filling column approximately 3/4 full with new packing material. HQ/MEHQ columns refill vol.: ~21g. TBC column refill vol.:~30g.
• Approx. column capacity:
HQ/MEHQ: 3L at 100ppm
TBC: 4L at 15ppm
• TBC columns and packings are not recommended for use with polar solvents, including acrylic acid. Vacuum distillation is suggested for such applications.
Easy-to-use:
1. Prewashing of prepacked glass columns with a small amount of monomer is recommended.
2. Add monomer (or solvent) to an addition funnel which is secured above column.
3. Add monomer dropwise to the column. Monitor rate of addition to prevent overflow of the column. Collect monomer in an appropriate container.
4. For low-melting solid monomers, keep temperature of column above the melting point during use.
Caution: Overheating may cause monomer to polymerize on the column. Viscous or high-melting monomers may be diluted in an appropriate solvent before addition to the column.
1Unused columns can be discarded with other solid chemical waste. After use, the toxicity and hazards of the monomer, from which the inhibitor is being removed, should be considered in deciding how to dispose of the packing material or column.
• Useful in applications which require that the stabilizer or inhibitor (hydroquinone (HQ), hydro-quinone monomethyl ether (MEHQ, 4-methoxyphenol), or 4-tert-butylcatechol (TBC) be removed prior to use.
• Columns may be discarded1 when exhausted or reused by filling column approximately 3/4 full with new packing material. HQ/MEHQ columns refill vol.: ~21g. TBC column refill vol.:~30g.
• Approx. column capacity:
HQ/MEHQ: 3L at 100ppm
TBC: 4L at 15ppm
• TBC columns and packings are not recommended for use with polar solvents, including acrylic acid. Vacuum distillation is suggested for such applications.
Easy-to-use:
1. Prewashing of prepacked glass columns with a small amount of monomer is recommended.
2. Add monomer (or solvent) to an addition funnel which is secured above column.
3. Add monomer dropwise to the column. Monitor rate of addition to prevent overflow of the column. Collect monomer in an appropriate container.
4. For low-melting solid monomers, keep temperature of column above the melting point during use.
Caution: Overheating may cause monomer to polymerize on the column. Viscous or high-melting monomers may be diluted in an appropriate solvent before addition to the column.
1Unused columns can be discarded with other solid chemical waste. After use, the toxicity and hazards of the monomer, from which the inhibitor is being removed, should be considered in deciding how to dispose of the packing material or column.
Application
Inhibitor remover is mainly used in the purification of methyl methacrylate monomer (MMA) and the removal of hydroquinone, which can be used for the synthesis of polymethyl methacrylate (PMMA). It can also be used to purify and remove the inhibitor in N,N-dimethylacrylamide (DMAA) and hydroxylethyl methacrylate (HEMA), that can be used to fabricate a low-cost absorbent for metal absorption.
1 of 1
This Item | |||
|---|---|---|---|
| form beads | form powder | form powder | form beads |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| column size 17 mm × 240 mm | column size - | column size - | column size - |
| vapor pressure 17 mmHg ( 20 °C) | vapor pressure 17 mmHg ( 20 °C) | vapor pressure 17 mmHg ( 20 °C) | vapor pressure 17 mmHg ( 20 °C) |
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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I want to use it for removing MEHQ from MPC. Can i do this way? prepare MPC in methanol solution, for example 30 mL solution(Conc?), then pass through the column. Do i need to use additional methanol (e.g. another 20mL) to help MPC elute out completely?
1 answer-
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How can I determine the shelf life / expiration / retest date of this product?
1 answer-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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お世話になります。御社製品のInhibitor removers(306312-1EA)を、学内ルールに基づきまして廃棄したく思っております。 つきましては、以下につきましてご確認いただきご回答いただきたく思っております。 1.水銀または遊離シアンを含んでいないこと（ルール上念の為お伺いいたします）。 2.製品の物質名（SDSをインターネット上で拝見いたしましたが、物質名の記載がありませんでしたのでお伺いいたします。）
1 answer-
This product does not contain mercury or free cyanide. Unfortunately, the identity of the hydroquinone and MEHQ remover is proprietary and cannot be disclosed.
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Would these work for removal of Topanol A, 2,4-Dimethyl-6-tert-butylphenol CAS Number:1879-09-0?
1 answer-
This product is not tested for removal of Topanol A, but is expected to be suitable. The product is used for inhibitor removal for product 276685. Methacrylic anhydride, which contains 2,000 ppm Topanol A as inhibitor.
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Which side of the column is the top versus the bottom?
1 answer-
The label is placed at the top of the column and will include the lot number. The column is provided with a cap on each end; these caps would need to be removed when the column is in use, but replaced between uses.
The glass wool plugs are present to hold the beads inside the column. Initially, a small volume of liquid will wet the glass wool. As more volume is added, the column will become saturated and then eventually pass through and out at the bottom of the column.
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What is the flow rate for Product 306312, Inhibitor removers - Prepacked column for removing hydroquinone and monomethyl ether hydroquinone?
1 answer-
According to the manufacturer of this inhibitor removal column, the maximum recommended flow rate is 4 bed volumes (approximately 120 mL) per hour.
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Can Product 306312, Inhibitor removers - Prepacked column for removing hydroquinone and monomethyl ether hydroquinone, be used more than once?
1 answer-
This pre-packed inhibitor remover column is meant for single use but can be rinsed and reused. If time will pass between uses, this column can be rinsed with methanol, dried, capped on both ends, and stored in a tightly sealed plastic bag in the freezer at -20°C.
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Can Product 306312, Inhibitor removers - Prepacked column for removing hydroquinone and monomethyl ether hydroquinone, be used to remove butylated hydroxytoluene (BHT)?
1 answer-
This inhibitor remover is not intended to remove BHT present in a monomer solution; little, if any, BHT will be removed with this column. Unfortunately, Sigma-Aldrich does not currently offer a inhibitor-remover column that will accomplish this purpose.
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How much can Product 306312, Inhibitor removers - Prepacked column for removing hydroquinone and monomethyl ether hydroquinone, hold at one time?
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This product has a bed volume of approximately 30 mL.
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