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Thiophanate-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C12H14N4O4S2
CAS Number:
23564-05-8
Molecular Weight:
342.39
Beilstein/REAXYS Number:
937942
EC Number:
245-740-7
MDL number:
MFCD00055294
UNSPSC Code:
41116107
PubChem Substance ID:
329756901
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

COC(=O)NC(=S)Nc1ccccc1NC(=S)NC(=O)OC

InChI

1S/C12H14N4O4S2/c1-19-11(17)15-9(21)13-7-5-3-4-6-8(7)14-10(22)16-12(18)20-2/h3-6H,1-2H3,(H2,13,15,17,21)(H2,14,16,18,22)

Inchi Key

QGHREAKMXXNCOA-UHFFFAOYSA-N

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General description

Thiophanate-methyl is a systemic benzimidazole fungicide, commonly used in agriculture for the pre- and post-harvest treatment of pathogen affecting a variety of fruits and vegetables.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Thiophanate-methyl may be used as an analytical reference standard for the quantification of the analyte in fruits, and wines using different chromatography techniques.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF5844
BCBV5376
BCBS9727V
SZBC220XV
SZBA146XV

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Determination of carbendazim, thiabendazole and thiophanate-methyl in banana (Musa acuminata) samples imported to Italy
Veneziano A, et al.
Food Chemistry, 87(3), 383-386 (2004)
Darshan M Rudakiya et al.
International journal of biological macromolecules, 144, 586-595 (2019-12-13)
Laccase from previously reported hardwood degrading fungus, Tricholoma giganteum AGDR1, was isolated, identified at molecular level, biochemically characterized and also utilized for pesticide degradation. Laccase gene is comprised of 3752 bp, which encompassed 742-bp of 5' flanking upstream sequence with 12
Mariusz Cycoń et al.
Biodegradation, 22(3), 573-583 (2010-10-27)
Degradation of the fungicide thiophanate-methyl (TM) by Enterobacter sp. TDS-1 and Bacillus sp. TDS-2 isolated from sandy soil previously treated with TM was studied in mineral salt medium (MSM) and soil. Both strains were able to grow in MSM supplemented
T Capriglione et al.
Ecotoxicology (London, England), 20(4), 885-891 (2011-04-05)
The increasing use of pesticides in modern agriculture has raised the need to evaluate their potential threat to animal and human health. In the present study, the genotoxic effects of environmentally relevant exposure to the fungicide thiophanate-methyl (TM) were assessed
Sufang Fan et al.
Bulletin of environmental contamination and toxicology, 90(4), 477-481 (2012-12-18)
To select representative crop among leaf vegetables which may contain the highest residue after fungicide uses, open field applications with thiophanate-methyl on six crops including pakchoi, rape, crown daisy, amaranth, spinach and lettuce were designed and conducted. In this study
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