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375187

Sigma-Aldrich

Trimethyltin chloride solution

1.0 M in hexanes

Synonym(s):

Chlorotrimethylstannane, Chlorotrimethyltin, Trimethylchlorostannane, Trimethylchlorotin, Trimethylstannyl chloride, Trimethyltin chloride

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About This Item

Linear Formula:
(CH3)3SnCl
CAS Number:
Molecular Weight:
199.27
Beilstein/REAXYS Number:
3535111
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

form

liquid

concentration

1.0 M in hexanes

density

0.797 g/mL at 25 °C

SMILES string

C[Sn](C)(C)Cl

InChI

1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1

InChI key

KWTSZCJMWHGPOS-UHFFFAOYSA-M

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Application

Trimethyltin chloride solution (1.0 M in hexanes) can be used as a reagent in the synthesis of conjugated polymers based on isoindigo as acceptor and syn- or anti-benzo[1,2-b:5,4-b′]difuran (BDF) as a donor by Stille cross-coupling reaction. It can further be used for the investigation of optical, electrochemical and photovoltaic properties.

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-9.4 °F - closed cup

flash_point_c

-23 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis and photovoltaic properties of new conjugated polymers based on syn-and anti-benzodifuran
Hu C, et al.
Polym. Chem., 3(10), 2949-2955 (2012)
Xiaojiang Tang et al.
Toxicology, 271(1-2), 45-50 (2010-03-10)
Trimethyltin chloride (TMT), a byproduct of plastic stabilizers, has caused 67 poisoning accidents in the world; more than 98% (1814/1849) of the affected patients since 1998 have been in China. As a long-established toxic chemical, TMT severely affects the limbic
Katharina Krüger et al.
British journal of pharmacology, 144(2), 283-292 (2005-01-19)
1. Organotin compounds such as trimethyltin chloride (TMT) are among the most toxic of the organometallics. As their main target for toxicity is the central nervous system, the aim of the present study was to investigate the effects of TMT
Kiyokazu Ogita et al.
Journal of neuroscience research, 82(5), 609-621 (2005-11-08)
The hippocampal dentate gyrus in adult animals is known to contain neural progenitors that proliferate and differentiate into neurons in response to brain injury. Little has been observed, however, on regeneration of the granule cell layer of the dentate gyrus
Guangshu Zhai et al.
Chemosphere, 72(3), 389-399 (2008-04-25)
The photodegradation of methyltins, as environmental pollutants, has scarcely been studied so far because of the shortage of rapid and sensitive speciation methods, even though they have very simple structures. The photodegradation of monomethyltin trichloride (MMT), dimethyltin dichloride (DMT) and

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