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28625

Sigma-Aldrich

Cyanuric fluoride

Synonym(s):

2,4,6-Trifluoro-1,3,5-triazine

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About This Item

Empirical Formula (Hill Notation):
C3F3N3
CAS Number:
675-14-9
Molecular Weight:
135.05
Beilstein/REAXYS Number:
124237
EC Number:
211-620-8
MDL number:
MFCD00014597
UNSPSC Code:
12352101
PubChem Substance ID:
57648317

SMILES string

Fc1nc(F)nc(F)n1

InChI

1S/C3F3N3/c4-1-7-2(5)9-3(6)8-1

InChI key

VMKJWLXVLHBJNK-UHFFFAOYSA-N

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Caution

can precipitate on storage

Other Notes

Modifies tyrosyl residues in proteins; Reagent used for the preparation of carboxylic fluorides

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Eye Dam. 1 - Skin Corr. 1A

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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[43] cyanuration.
M J Gorbunoff
Methods in enzymology, 25, 506-514 (1972-01-01)
Tyrosyl residues of two molecular forms of human urinary urokinase: their ionization mode characterized by spectrophotometric and CD titrations and reactivity with cyanuric fluoride in relation to enzymic activity.
N Miwa et al.
Biochemical and biophysical research communications, 108(3), 1136-1143 (1982-10-15)
M.J.S. Dewar et al.
The Journal of Organic Chemistry, 40, 1521-1521 (1975)
Julia Laskin et al.
Journal of the American Society for Mass Spectrometry, 28(7), 1304-1312 (2017-03-16)
Using mass-selected ion deposition combined with in situ infrared reflection absorption spectroscopy (IRRAS), we examined the reactive landing of gramicidin S and ubiquitin ions onto activated self-assembled monolayer (SAM) surfaces terminated with N-hydroxysuccinimidyl ester (NHS-SAM) and acyl fluoride (COF-SAM) groups.
Chemical reactivity of the tyrosyl residues in yeast hexokinase. Properties of the nitroenzyme.
G Coffe et al.
Biochimica et biophysica acta, 484(2), 322-335 (1977-10-13)
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