232173

S,S-Diphenylsulfilimine monohydrate

97%

• Linear Formula: (C₆H₅)₂S=NH · H₂O
• CAS Number: 68837-61-6
• Molecular Weight: 219.30
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24853884
• MDL number: MFCD00149076
• Beilstein/REAXYS Number: 2043848
• Assay: 97%
• Form: powder

Properties

• assay: 97%
• form: powder
• mp: 67-71 °C (lit.)
• functional group: thioether
• SMILES string: [H]O[H].N=S(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11NS.H2O/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10,13H;1H2
• InChI key: YLGYIQQZVOCMDO-UHFFFAOYSA-N

Description

General description

Kinetics and mechanism of reaction of S,S-diphenylsulfilimine with 1-fluoro-2,4-dinitrobenzene, 1-chloro-2,4-dinitrobenzene, 2-chloro-3-nitropyridine, 2-chloro-5-nitropyridine and 2-chloro-3,5-dinitropyridine has been investigated.

Application

S,S-Diphenylsulfilimine monohydrate is a versatile synthetic tool and has been used in preparation of:

• N-(5-nitrosouracil-6-yl)sulfilimines
• N-(1,3-dimethyl-6-uracilyl)-S,S-diphenylsulfilimines
• N-(5-formyl-1,3-dimethyl-6-uracilyl)-S,S-diphenylsulfilimines

Safety Information

• Storage Class: 11 - Combustible Solids
• WGK: WGK 3