206547
4-Iodobenzoic acid
98%
Synonym(s):
4-Iodobenzoic acid, Iodobenzene-4-carboxylic acid, p-Iodobenzenecarboxylic acid, p-Iodobenzoic acid
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About This Item
Linear Formula:
IC6H4CO2H
CAS Number:
Molecular Weight:
248.02
Beilstein/REAXYS Number:
1860232
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
98%
mp
270-273 °C (lit.)
functional group
carboxylic acid
SMILES string
OC(=O)c1ccc(I)cc1
InChI
1S/C7H5IO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4H,(H,9,10)
InChI key
GHICCUXQJBDNRN-UHFFFAOYSA-N
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Application
4-Iodobenzoic acid was used in the synthesis of [hydroxy(4-carboxyphenyl)iodonium]ion in situ that helps in the cleavage of a variety of alkenes.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Prem P Thottumkara et al.
Organic letters, 12(24), 5640-5643 (2010-11-18)
A facile and operationally convenient catalytic procedure for oxidative cleavage of alkenes is described. In situ formed [hydroxy(4-carboxyphenyl)iodonium]ion, 2, from the oxidation of 4-iodobenzoic acid, 1, has been shown to facilitate the cleavage of a variety of alkenes in presence
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