133159

Bathophenanthroline

97%

• Synonym(s): 4,7-Diphenyl-1,10-phenanthroline, BPhen
• Empirical Formula (Hill Notation): C₂₄H₁₆N₂
• CAS Number: 1662-01-7
• Molecular Weight: 332.40
• Beilstein/REAXYS Number: 261048
• EC Number: 216-767-1
• MDL number: MFCD00004976
• UNSPSC Code: 12352103
• PubChem Substance ID: 24848094
• NACRES: NA.23

Properties

• assay: 97%
• form: solid
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 218-220 °C (lit.)
• orbital energy: HOMO 6.4 eV ; LUMO 3 eV
• OLED device performance: ITO/MoO₃/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 20000 Cd/m²
  • Max. EQE: 1.2 %
  • Turn-On Voltage: 2.8 V
  ; ITO/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 19000 Cd/m²
  • Max. EQE: 1.16 %
  • Turn-On Voltage: 6.6 V
  ; ITO/PEDOT:PSS/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 14000 Cd/m²
  • Max. EQE: 1.44 %
  • Turn-On Voltage: 5 V
  ; ITO/PEDOT:PSS/PVK:Ir(mppy)₂ (6wt%)/BPhen/LiF:Al;
  • Color: green
  • Max. Luminance: 10000 Cd/m²
  • Max. EQE: 1.1 %
  • Turn-On Voltage: 3.8 V
  ; ITO/TCTA/Ir(ppy)₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 300000 Cd/m²
  • Max. EQE: 19 %
  • Turn-On Voltage: 2.6 V
  ; PEDOT:PSS/MoO₃/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 15000 Cd/m²
  • Max. EQE: 1.71 %
  • Turn-On Voltage: 2.3 V
• greener alternative category: Aligned,
• SMILES string: c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5
• InChI: 1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H
• InChI key: DHDHJYNTEFLIHY-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. For more information see the Green, Catalytic Oxidation of Alcohols in Water

Application

• Synthesis and luminescent properties of a ternary erbium (III) complex: A study on the luminescent properties of an erbium(III) complex with bathophenanthroline, which may have implications for materials science and sensor applications (Martín-Ramos et al., 2015).
• Aggregation induced emission enhancement from Bathophenanthroline microstructures: Investigation of bathophenanthroline microstructures that exhibit enhanced emission properties and potential use as sensors for detecting mercury ions in water (Mazumdar et al., 2014).

Other Notes

Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)