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271020

1,3-Dioxolane

anhydrous, contains ~75 ppm BHT as inhibitor, 99.8%

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Synonym(s):

Ethylene glycol methylene ether, Formaldehyde ethylene acetal

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Size/SKUAvailabilityPrice
100 mL

Available to ship TODAYfromMILWAUKEE

$60.10
1 L

Available to ship TODAYfromMILWAUKEE

$251.00
2 L

Available to ship TODAYfromMILWAUKEE

$547.00

About This Item

Linear Formula:
OCH2CH2OCH2
CAS Number:
Molecular Weight:
74.08
Beilstein/REAXYS Number:
102453
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
211-463-5
MDL number:
Assay:
99.8%
Grade:
anhydrous
Bp:
75-76 °C/1.013 hPa
Vapor pressure:
70 mmHg ( 20 °C)

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grade

anhydrous

Quality Segment

vapor density

2.6 (vs air)

vapor pressure

70 mmHg ( 20 °C)

assay

99.8%

form

liquid

autoignition temp.

525 °F

contains

~75 ppm BHT as inhibitor

impurities

<0.003% water, <0.005% water (100 mL pkg)

evapn. residue

<0.0005%

refractive index

n20/D 1.401 (lit.)

bp

75-76 °C/1.013 hPa

mp

−95 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

SMILES string

C1COCO1

InChI

1S/C3H6O2/c1-2-5-3-4-1/h1-3H2

InChI key

WNXJIVFYUVYPPR-UHFFFAOYSA-N

General description

Our anhydrous solvents deliver exceptionally low water content, making them the ideal choice for moisture-sensitive laboratory applications. Packaged in the exclusive Sure/Seal septum bottle system, they are reliably protected against moisture ingress from first use to last drop. The innovative Sure/Seal closure combines an advanced plug-style liner with an airtight elastomer and crimp cap design to ensure consistent product integrity. Three unique liner materials provide optimal chemical compatibility across a broad range of solvents. Sure/Seal packaging is proven to maintain anhydrous conditions even after repeated punctures. With more than 70 products across all major solvent families, available in pack sizes from 100 mL to 2 L, the portfolio meets virtually every laboratory need. By choosing ready-to-use anhydrous solvents in Sure/Seal packaging, researchers eliminate the need for time-consuming and hazardous in-house solvent drying and distillation - saving time, reducing risk, and improving reproducibility.

Application

Anhydrous solvents in Sure/Seal packaging are essential wherever water contamination would compromise experimental results. They are widely used in moisture-sensitive applications such as organic synthesis - including Grignard reactions, organometallic chemistry, and catalysis - as well as in peptide, oligonucleotide, and pharmaceutical synthesis.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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description

anhydrous, contains ~75 ppm BHT as inhibitor, 99.8%

description

97%

description

97%

description

ACS reagent, ≥99.0%, contains ≤50 ppm BHT as stabilizer

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

assay

99.8%

assay

97%

assay

97%

assay

≥99.0%

grade

anhydrous

grade

-

grade

-

grade

ACS reagent

form

liquid

form

liquid

form

-

form

liquid

mp

−95 °C (lit.)

mp

−45 °C (lit.)

mp

-

mp

10-12 °C (lit.)

bp

75-76 °C/1.013 hPa

bp

105-106 °C (lit.)

bp

82-83 °C (lit.)

bp

100-102 °C (lit.)


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signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

26.6 °F - closed cup

flash_point_c

-3 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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