72262

Nickel (IV) oxide

technical, ~30% active peroxide basis

• Synonym(s): Nickel dioxide, Nickel oxide
• Empirical Formula (Hill Notation): NiO₂
• CAS Number: 12035-36-8
• Molecular Weight: 90.69
• NACRES: NA.22
• PubChem Substance ID: 57652407
• UNSPSC Code: 12352000
• EC Number: 234-823-3
• MDL number: MFCD00011143

Properties

• Quality Segment: 100
• grade: technical
• form: powder
• reaction suitability: core: nickel, reagent type: catalyst, reagent type: oxidant
• concentration: ~30% (active peroxide)
• SMILES string: O=[Ni]O[Ni]=O
• InChI: 1S/2Ni.3O
• InChI key: PZFKDUMHDHEBLD-UHFFFAOYSA-N

Description

Application

Catalyst for:

• One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation
• Microwave induced catalytic degradation of crystal violet

Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters

Reagent:

• For solvent-free oxidation of alcohols†
• For chemoselective oxidation of organic compounds using inductive heating
• To improve the synthesis of methoxy cephalosporin′s intermediate

Other Notes

Oxidant for the transformation of alcohols into acids and hydrazones into diazoalkanes

Safety Information

• pictograms: GHS03,GHS08,GHS07
• signalword: Danger
• hcodes: H272,H317,H350i,H372,H413
• pcodes: P202 - P210 - P273 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Chronic 4 - Carc. 1A Inhalation - Ox. Sol. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges