677531

(S,S)-DACH-pyridyl Trost ligand

97%

• Synonym(s): (+)-N,N′-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), (1S,2S)-(+)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane, (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane, (1S,2S)-N,N′-1,2-Cyclohexanediylbis(2-pyridinecarboxamide)
• Empirical Formula (Hill Notation): C₁₈H₂₀N₄O₂
• Molecular Weight: 324.38
• UNSPSC Code: 12352005
• PubChem Substance ID: 24885381
• MDL number: MFCD02684544

Properties

• assay: 97%
• mp: 171-176 °C
• SMILES string: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccn2)c3ccccn3
• InChI: 1S/C18H20N4O2/c23-17(15-9-3-5-11-19-15)21-13-7-1-2-8-14(13)22-18(24)16-10-4-6-12-20-16/h3-6,9-14H,1-2,7-8H2,(H,21,23)(H,22,24)/t13-,14-/m0/s1
• InChI key: BVYFDUZVVBXFBQ-KBPBESRZSA-N

Description

Application

Trost Ligands for Asymmetric Allylic Alkylation

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Codes: H302,H315,H319,H335
• Precautionary Statements: P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• PPE (personal protective equipment): dust mask type N95 (US), Eyeshields, Gloves