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516953

Sigma-Aldrich

Mercury(II) nitrate monohydrate

≥99.99% trace metals basis

Synonym(s):

Mercuric nitrate monohydrate

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About This Item

Linear Formula:
Hg(NO3)2 · H2O
CAS Number:
Molecular Weight:
342.62
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

assay

≥99.99% trace metals basis

reaction suitability

core: mercury
reagent type: catalyst

impurities

<100 ppm total metallic impurities

reduction residue

≤0.01%

mp

79 °C (lit.)

anion traces

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.002%

cation traces

Fe: ≤0.001%
Hg+: ≤0.2%

SMILES string

O.[Hg++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Hg.2NO3.H2O/c;2*2-1(3)4;/h;;;1H2/q+2;2*-1;

InChI key

KVICROHOONHSRH-UHFFFAOYSA-N

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Application

Reagent for oxymercuration; amidomercuration; cyclopropanecleavage; glycosylation

Features and Benefits

Meets A.C.S. reagent specifications.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fry, A. J.; Simon, J. A.
The Journal of Organic Chemistry, 47, 5032-5032 (1982)
Wiesner, K.; Tsai, T. Y. R.; Jin, H.
Helvetica Chimica Acta, 68, 300-300 (1985)
Collum, D. B.; Still, W. C.; Mohamadi, F.
Journal of the American Chemical Society, 105, 6882-6882 (1983)
Kocovsky, P.,
Organometallic News, 12, 1969-1969 (1993)

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