If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
481130
Gold(I) chloride
99.9% trace metals basis
Synonym(s):
Aurous chloride, Gold monochloride
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About This Item
Recommended Products
grade
for analytical purposes
assay
99.9% trace metals basis
form
powder
reaction suitability
reagent type: catalyst
core: gold
impurities
≤1500 ppm Trace Metal Analysis
mp
289 °C (dec.) (lit.)
density
7.57 g/mL at 25 °C (lit.)
SMILES string
[Cl-].[Au+]
InChI
1S/Au.ClH/h;1H/q+1;/p-1
InChI key
FDWREHZXQUYJFJ-UHFFFAOYSA-M
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General description
Application
- As a precursor to prepare magnetic nanocatalyst systems for various organic transformations. For example, Fe3O4@SiO2-P–AuCl can be used as a catalyst for one-pot reductive amination of aldehydes and ketones with various aromatic amines.[1]
- As a starting material to synthesize Au-containing complexes for application in the field of drug delivery, solar cells, sensors, and organic synthesis.[2]
- As a precatalyst for stereoselective cycloisomerization of α-thioallenes to 2,5-dihydrothiophenes via C-S bond formation.[3]
- As a catalyst for the conversion of siloxy cyclohexadienes, to the corresponding1,2- and 1,3-cyclohexenones via Gold-Catalyzed Cycloisomerization.[4]
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - Skin Sens. 1
Storage Class
8A - Combustible corrosive hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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