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441805

Sigma-Aldrich

Tris(nonylphenyl) phosphite

Synonym(s):

Tri(monononylphenyl) phosphite

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250 ML
$44.84

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250 ML
$44.84

About This Item

Linear Formula:
(C9H19C6H4O)3P
CAS Number:
Molecular Weight:
689.00
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

$44.84

List Price$47.20

In StockDetails


Request a Bulk Order

form

liquid

Quality Level

refractive index

n20/D 1.528 (lit.)

bp

>360 °C (lit.)

density

0.99 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCc1ccccc1OP(Oc2ccccc2CCCCCCCCC)Oc3ccccc3CCCCCCCCC

InChI

1S/C45H69O3P/c1-4-7-10-13-16-19-22-31-40-34-25-28-37-43(40)46-49(47-44-38-29-26-35-41(44)32-23-20-17-14-11-8-5-2)48-45-39-30-27-36-42(45)33-24-21-18-15-12-9-6-3/h25-30,34-39H,4-24,31-33H2,1-3H3

InChI key

WGKLOLBTFWFKOD-UHFFFAOYSA-N

General description

Tris(nonylphenyl) phosphite (TNPP) is an antioxidant that is majorly used as a stabilizer to improve the performance of polyethylene by decomposing the hydroperoxides. It can also be used to enhance the thermal stability by extending the polymeric chains. [1][2]

Application

TNPP in combination with irganox is used to protect polyamide 6 (PA6) from oxidative degradation during the preparation of flame retardant nanocomposites.[3] TNPP can be used as a stabilizer that prevents the molecular weight reduction and increases the tensile strength of the composite.[4] It can also be used as a chain extender to improve the polymeric viscosity during the melt-blending of poly(hydroxybutyrate-co-hydroxyvalerate) based clay nanocomposites which find potential application as packaging materials.[5]

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

404.6 °F - closed cup

flash_point_c

207 °C - closed cup

ppe

Eyeshields, Gloves


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Bio-based solution-cast blend films based on polylactic acid and polyhydroxybutyrate: Influence of pyromellitic dianhydride as chain extender on the morphology, dispersibility, and crystallinity
Dawin TP, et al.
Progress in Organic Coatings, 119(5), 23-30 (2018)
LC-MS/MS analytical procedure to quantify tris (nonylphenyl) phosphite, as a source of the endocrine disruptors 4-nonylphenols, in food packaging materials
Mottier P, et al.
Food Additives & Contaminants. Part A, Chemistry, Analysis, Control, Exposure & Risk Assessment, 31(5), 962-972 (2014)
Halloysite nanotubes loaded with liquid organophosphate for enhanced flame retardancy and mechanical properties of polyamide 6
Boonkongkaew M and Sirisinha K
Journal of materials science & technology, 119(5), 1-13 (2018)
On the use of tris (nonylphenyl) phosphite as a chain extender in melt-blended poly (hydroxybutyrate-co-hydroxyvalerate)/clay nanocomposites: Morphology, thermal stability, and mechanical properties
Gonzalez?Ausejo J, et al.
Journal of Applied Polymer Science, 133(2), 118-129 (2016)
Effects of chain-extending stabilizer on bioplastic poly (lactic acid)/polyamide blends compatibilized by reactive extrusion
Gug J, et al.
Polymer Degradation and Stability, 153(5), 118-129 (2018)

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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