380237
Tebbe reagent solution
0.5 M in toluene
Synonym(s):
Bis(cyclopentadienyl)-μ-chloro(dimethylaluminum)-μ-methylenetitanium
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
25 mL | Check Cart for Availability | $325.00 |
4 x 25 mL | Estimated to ship TODAYfromMILWAUKEE | $529.00 |
100 mL | Check Cart for Availability | $1,230.00 |
About This Item
form
liquid
Quality Segment
reaction suitability
reaction type: C-C Bond Formation
concentration
0.5 M in toluene
density
0.927 g/mL at 25 °C
SMILES string
[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C[Al](C)C[Ti]Cl
InChI
1S/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/q;;;;;;;+1/p-1
InChI key
QEJAQNUJXFLWSP-UHFFFAOYSA-M
General description
Application
- For the conversion of carbonyl groups of chlorophyll derivatives into the corresponding exo-methylene (or vinylidene) groups.
- In the synthesis of β-C-glycosides from 3-OH glycol esters.
- As a versatile methylenation reagent for the conversion of ketones and aldehydes to olefins. It offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.
- To olefinate aldehydes.
- To methylenate a chiral polyhydroxyketone with high diasteroselctivity.
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 0.5 M in toluene | description 2 M in THF | description 2.0 M in hexanes | description 95% |
| reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation | reaction suitability - | reaction suitability reaction type: C-C Bond Formation |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| concentration 0.5 M in toluene | concentration 2 M in THF | concentration 2.0 M in hexanes | concentration - |
| density 0.927 g/mL at 25 °C | density 0.91 g/mL at 20 °C | density 0.683 g/mL at 25 °C | density 1.293 g/mL at 25 °C (lit.), 1.3178 g/mL at 25 °C |
| form liquid | form liquid | form liquid | form liquid |
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
39.2 °F - closed cup
flash_point_c
4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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