268658

N,N′-Bis(salicylidene)ethylenediaminonickel(II)

98%

• Synonym(s): Nickel(II) salen, [[α,α′-(Ethylenedinitrilo)di-o-cresolato](2-)]nickel, [[2,2′-[1,2-Ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]nickel
• Linear Formula: [-CH₂N=CHC₆H₄-2-(O-)]₂Ni
• CAS Number: 14167-20-5
• Molecular Weight: 324.99
• MDL number: MFCD00012041
• UNSPSC Code: 12352300
• PubChem Substance ID: 24856287

Properties

• assay: 98%
• reaction suitability: core: nickel; reagent type: catalyst
• SMILES string: C1C\N=C\c2ccccc2O[Ni]Oc3ccccc3\C=N\1
• InChI: 1S/C16H16N2O2.Ni/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+;
• InChI key: DKBSGGSJQXGHBV-OYJDLGDISA-L

Description

Application

Catalyst for:

• Covalent functionalization of multiwall carbon nanotubes
• Reduction reactions
• Epoxidation reactions
• Reduction and intramolecular cyclization

Safety Information

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H302 + H312 + H332,H315,H317,H319,H334,H335,H350
• pcodes: P202 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges