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255114

Sigma-Aldrich

3-Nitroanisole

99%

Synonym(s):

1-Methoxy-3-nitrobenzene

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About This Item

Linear Formula:
O2NC6H4OCH3
CAS Number:
555-03-3
Molecular Weight:
153.14
Beilstein/REAXYS Number:
1865326
EC Number:
209-079-8
MDL number:
MFCD00007237
UNSPSC Code:
12352100
PubChem Substance ID:
24855288
NACRES:
NA.22

assay

99%

form

solid

bp

121-123 °C/8 mmHg (lit.)

mp

36-38 °C (lit.)

solubility

alcohol: soluble(lit.)
water: insoluble(lit.)

SMILES string

COc1cccc(c1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3

InChI key

WGYFINWERLNPHR-UHFFFAOYSA-N

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General description

Photoinduced nucleophilic substitution reactions of 3-nitroanisole in the presence of OH− in mixtures of H2O and CH3CN and in the presence of OCH3− in CH3OH were investigated by nanosecond time-resolved absorption spectroscopy. 3-Nitroanisole undergoes photoreaction with n-butylamine to yield 3-nitrophenol. It forms a 1:1 inclusion complex with β-cyclodextrin in aqueous buffer solution at pH 12.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Spectroscopic and kinetic study of the photoinduced methoxy substitution of 3-nitroanisole and 3, 5-dinitroanisole.
Van Zeijl PHM, et al.
Journal of Photochemistry, 29(3), 415-433 (1985)
Modification of an intermolecular photoreaction by cyclodextrin: the photohydroxylation of 3-nitroanisole.
Evans CH and Gunnlaugsson T.
Journal of Photochemistry and Photobiology A: Chemistry, 78(1), 57-62 (1994)
Nitrophenyl ethers as possible photoaffinity labels. The nucleophilic aromatic photosubstitution revisited.
Cervelo J., et al.
Tetrahedron Letters, 25(37), 4147-4150 (1984)

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