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234826

Sigma-Aldrich

Bis(cyclopentadienyl)titanium(IV) dichloride

97%

Synonym(s):

Cp2TiCl2, Dichlorobis(1,3-cyclopentadiene)titanium, Dichlorodicyclopentadienyltitanium, Dichlorotitanocene, Cp2TiCl2, Di(cyclopentadienyl)titanium(IV) dichloride, Titanocene dichloride

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10 G
$56.90
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$187.00

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10 G
$56.90
50 G
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About This Item

Empirical Formula (Hill Notation):
C10H10Cl2Ti
CAS Number:
1271-19-8
Molecular Weight:
248.96
EC Number:
215-035-9
MDL number:
MFCD00003723
UNSPSC Code:
12161600
PubChem Substance ID:
24854058
NACRES:
NA.22

$56.90

Available to ship onApril 22, 2025Details

Request a Bulk Order

Quality Level

100

assay

97%

reaction suitability

core: titanium
reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

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Application

One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates.[1]

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBK7215
STBK4429
STBK1876
STBJ2898
STBH8972

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Alberto García-Peñas et al.
Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)
Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)
Katherine M Buettner et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)
Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is
Ping Chen et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 76(3), 413-420 (2010-09-22)
In order to improve both safety and efficacy of cancer chemotherapy of titanocene dichloride and overcome the shortcomings such as instability and short half-life in the human body, we report a controlled release system of titanocene dichloride by electrospun fiber
Francesco Caruso et al.
Mini reviews in medicinal chemistry, 4(1), 49-60 (2004-02-03)
Most anticancer titanium compounds act against tumors in the gastrointestinal tract. Activity towards breast, lung and skin (melanoma) cancers is shown by some as well. Among their appealing properties is that they do not show common side effects of widely
Mauro Ravera et al.
Journal of inorganic biochemistry, 99(12), 2264-2269 (2005-10-08)
Titanocene dichloride exhibits anti-proliferative activity in a wide spectrum of murine and human tumors. Although it is still unclear as to which species are active in biological media, they all readily deliver Ti(IV) to transferrin, the protein that transports iron
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      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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