If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
226084
(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate
97%, for peptide synthesis
Synonym(s):
BOP, BOP Reagent, Castros reagent
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Available to ship TODAYfromMILWAUKEE | $64.80 |
5 g | Available to ship TODAYfromMILWAUKEE | $101.00 |
About This Item
Product Name
(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate, 97%
Quality Segment
assay
97%
form
powder
reaction suitability
reaction type: Coupling Reactions
mp
>130 °C (dec.) (lit.)
application(s)
peptide synthesis
functional group
amine
storage temp.
2-8°C
SMILES string
F[P-](F)(F)(F)(F)F.CN(C)[P+](On1nnc2ccccc12)(N(C)C)N(C)C
InChI
1S/C12H22N6OP.F6P/c1-15(2)20(16(3)4,17(5)6)19-18-12-10-8-7-9-11(12)13-14-18;1-7(2,3,4,5)6/h7-10H,1-6H3;/q+1;-1
InChI key
MGEVGECQZUIPSV-UHFFFAOYSA-N
Application
Peptide coupling
Synthesis of esters
Esterification of carboxylic acids
Plasmid CAN-encapsulating liposomes[1]
Synthesis of magnolamide for antioxidative activity
Catalyst for preparation of 9-acridinecaroboxamide derivative
1 of 1
This Item | |||
|---|---|---|---|
| form powder | form powder | form powder | form solid |
| assay 97% | assay ≥99.0% (HPLC) | assay - | assay - |
| functional group amine | functional group - | functional group - | functional group - |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| mp >130 °C (dec.) (lit.) | mp 138-145 °C | mp - | mp - |
| reaction suitability reaction type: Coupling Reactions | reaction suitability reaction type: Coupling Reactions | reaction suitability - | reaction suitability - |
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
4.1A - Other explosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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