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219584

2,6-Di-tert-butylpyridine

≥97%

Synonym(s):

2,6-Bis(1,1-dimethylethyl)pyridine, 2,6-Ditert-butylpyridine

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Size/SKUAvailabilityPrice
1 g
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$61.10
5 g
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$212.00
25 g
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$544.00

About This Item

Empirical Formula (Hill Notation):
C13H21N
CAS Number:
Molecular Weight:
191.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-557-6
Beilstein/REAXYS Number:
125886
MDL number:
Assay:
≥97%
Form:
liquid

$61.10


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Quality Segment

assay

≥97%

form

liquid

refractive index

n20/D 1.473 (lit.)

bp

100-101 °C/23 mmHg (lit.)

density

0.852 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)(C)c1cccc(n1)C(C)(C)C

InChI

1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3

InChI key

UWKQJZCTQGMHKD-UHFFFAOYSA-N

General description

Reactivity of 2,6-di-tert-butylpyridine with iron(III) tetraphenylporphyrin pi-cation radical has been examined by proton NMR spectroscopy. Reaction of 2,6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure has been reported.

Application

2,6-Di-tert-butylpyridine was used as proton trapping agent to investigate the living polymerization of isobutylene. It was also used with cerric ammonium nitrate in the α-enolation of aldehydes leading to 1,4-dicarbonyl systems.

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549967193801372110
description

≥97%

description

97%

description

99%

description

96%

assay

≥97%

assay

97%

assay

99%

assay

96%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

density

0.852 g/mL at 25 °C (lit.)

density

-

density

-

density

0.902 g/mL at 25 °C (lit.)

bp

100-101 °C/23 mmHg (lit.)

bp

-

bp

190-192 °C/13 mmHg (lit.)

bp

141-142 °C/10 mmHg (lit.)

refractive index

n20/D 1.473 (lit.)

refractive index

-

refractive index

-

refractive index

-

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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