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203548

Lanthanum(III) nitrate hexahydrate

99.999% trace metals basis

Synonym(s):

Nitric acid, lanthanum (III) salt, hexahydrate

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Size/SKUAvailabilityPrice
25 g
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$114.00
100 g
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$281.00
500 g
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$979.00

About This Item

Linear Formula:
La(NO3)3 · 6H2O
CAS Number:
Molecular Weight:
433.01
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-238-0
MDL number:
Assay:
99.999% trace metals basis
Form:
solid

$114.00


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Quality Segment

assay

99.999% trace metals basis

form

solid

reaction suitability

core: lanthanum, reagent type: catalyst

impurities

≤15.0 ppm Trace Rare Earth Analysis

mp

65-68 °C

application(s)

electroplating
material synthesis precursor

SMILES string

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

InChI key

GJKFIJKSBFYMQK-UHFFFAOYSA-N

General description

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.

Application

Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:
  • α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
  • Acetals and geminal diacetates (acylals)from aldehydes.
  • Bis(indolyl) methanes under solvent‐free conditions.
It can also be used as a starting material for the electrochemical synthesis of LaMnO3 thin films and solvothermal synthesis of doped lanthanide oxysulfide (La2O2S).

Features and Benefits

  • Thermal stability
  • Low toxicity
  • Mild reaction condition
  • Chemoselectivity
  • Low cost

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This Item
238554331937203521
form

solid

form

(powder, crystals or chunks)

form

solid

form

solid

assay

99.999% trace metals basis

assay

99.9% trace metals basis

assay

99.99% trace metals basis

assay

99.999% trace metals basis

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

mp

65-68 °C

mp

-

mp

65-68 °C

mp

91 °C (dec.) (lit.)

impurities

≤15.0 ppm Trace Rare Earth Analysis

impurities

≤2000.0 ppm Trace Rare Earth Analysis

impurities

≤150.0 ppm Trace Rare Earth Analysis

impurities

≤15.0 ppm Trace Rare Earth Analysis

application(s)

electroplating
material synthesis precursor

application(s)

-

application(s)

electroplating
material synthesis precursor

application(s)

electroplating
material synthesis precursor


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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 2

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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