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195529
Iodotrimethylsilane
97%
Synonym(s):
TMIS, Trimethyliodosilane
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 g | Estimated to ship onOctober 05, 2026fromMILWAUKEE | $54.70 |
25 g | Estimated to ship onOctober 05, 2026fromMILWAUKEE | $142.00 |
100 g | Estimated to ship onOctober 05, 2026fromMILWAUKEE | $318.00 |
About This Item
Quality Segment
assay
97%
form
liquid
contains
copper as stabilizer
reaction suitability
reactivity: alcohol reactive, reagent type: protection reagent
refractive index
n
bp
106 °C (lit.)
density
1.406 g/mL at 25 °C (lit.)
functional group
silyl
storage temp.
−20°C
SMILES string
C[Si](C)(C)I
InChI
1S/C3H9ISi/c1-5(2,3)4/h1-3H3
InChI key
CSRZQMIRAZTJOY-UHFFFAOYSA-N
General description
Iodotrimethylsilane is a hard-soft reagent that reacts readily with organic compounds containing oxygen (a hard base) forming a strong siliconoxygen bond.
Application
Disclaimer
1 of 1
This Item | |||
|---|---|---|---|
| description 97% | description 1 M in dichloromethane | description 97% | description 99.9% |
| assay 97% | assay - | assay 97% | assay 99.9% |
| Quality Level 300 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| form liquid | form liquid | form - | form - |
| refractive index n | refractive index n | refractive index n | refractive index - |
| density 1.406 g/mL at 25 °C (lit.) | density 1.334 g/mL at 25 °C | density 0.811 g/mL at 25 °C (lit.) | density - |
| bp 106 °C (lit.) | bp - | bp - | bp - |
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-23.8 °F - closed cup
flash_point_c
-31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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What is known of the mechanism of reactions involving product 195529, Iodotrimethylsilane?
1 answer-
The mechanism for cleavage of esters is described in PNAS, 75(1), 4-6 (1978).The authors go on to explain that the data do not support a previously published mechanism via a carbenium iodide.The paper also discusses the cleavage of ethers using iodotrimethylsilane. It appears that this is not as efficient as cleavage of esters, and a couple of mechanisms (pages 5 and 6) are proposed.Olah also described the cleavage of the phosphate esters in peptides that contain phosphate esters, using iodotrimethylsilane (Tetrahedron, 38, 2225 (1982)). The amide linkages in the peptide backbone are not cleaved.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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