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181781

Poly(2,6-dimethyl-1,4-phenylene oxide)

powder

Synonym(s):

2,6-Dimethyl-1,4-phenylene ether homopolymer, 2,6-Dimethylphenol homopolymer, 2,6-Dimethylphenol polymer, Poly(2,6-dimethylphenylene oxide)

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Size/SKUAvailabilityPrice
250 g

Available to ship onJune 17, 2026fromMILWAUKEE

$164.00

About This Item

Linear Formula:
[C6H2(CH3)2O]n
CAS Number:
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:

$164.00


Available to ship onJune 17, 2026Details


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form

powder

Quality Segment

transition temp

Tg 211 °C, Tm 268 °C

density

1.06 g/mL at 25 °C (lit.)

SMILES string

Cc1cc(O)cc(C)c1O

InChI

1S/C8H10O/c1-6-4-3-5-7(2)8(6)9/h3-5,9H,1-2H3

InChI key

NXXYKOUNUYWIHA-UHFFFAOYSA-N

General description

Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) is an anion exchange membrane (AEM) material that is mainly used as a cross-linker in which the methyl groups are used to bond with ultraviolet (UV) excited ketones.

Application

Imidazolium modified PPO with liquid ionic graphene oxide can be used as an anion exchange membrane (AEM) composite with a peak power density of 136 mW cm−2 for use in the fabrication of high performance fuel cells. It may also be sulfonated to form a long chained polymeric structure with an efficiency of 81.8% at a current density of 120 mA cm−2 for potentiall use in vanadium redox flow batteries (VRFBs) as effective energy storage systems. It may also be used in the formation of AEMs, which can be used in the development of microbial desalination cell system (MDCS).

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472360181803191094
form

powder

form

granular

form

powder

form

pellets

density

1.06 g/mL at 25 °C (lit.)

density

1.37 g/mL at 25 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

density

1.37 g/mL at 25 °C (lit.)

transition temp

Tg 211 °C, Tm 268 °C

transition temp

Tg (DSC) 221 °C (onset)

transition temp

-

transition temp

Tm (DSC) 213 °C (onset)

Quality Level

100

Quality Level

-

Quality Level

200

Quality Level

200


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Questions

1–4 of 4 Questions  
  1. Is this Quartenized or just a PPO alone?

    1 answer
    1. As indicated by the structure and CAS number, this product is unmodified PPO.

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. May I know the average molecular weight of the polymer?

    1 answer
    1. The approximate molecular weight for this product is 50,000 g/mol.

      Helpful?

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