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Sigma-Aldrich

Thallium(III) nitrate trihydrate

Synonym(s):

TTN, Thallium trinitrate

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About This Item

Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
13453-38-8
Molecular Weight:
444.44
EC Number:
237-325-4
MDL number:
MFCD00149874
UNSPSC Code:
12161600
PubChem Substance ID:
24850018
NACRES:
NA.22

reaction suitability

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES string

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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