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159042

Luperox® P, tert-Butyl peroxybenzoate

98%

Synonym(s):

tert-Butyl peroxybenzoate, tert-Butyl perbenzoate

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$13.50
100 g

Available to ship TODAYfromMILWAUKEE

$36.30
500 g

Available to ship TODAYfromMILWAUKEE

$175.00

About This Item

Linear Formula:
C6H5COOOC(CH3)3
CAS Number:
Molecular Weight:
194.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-382-2
Beilstein/REAXYS Number:
1342734
MDL number:
Assay:
98%
Form:
liquid

$13.50


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vapor density

6.7 (vs air)

Quality Segment

vapor pressure

3.36 mmHg ( 50 °C)

assay

98%

form

liquid

refractive index

n20/D 1.499 (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

solubility

water: soluble 1.18 g/L

density

1.021 g/mL at 25 °C (lit.)

functional group

peroxide, phenyl

SMILES string

CC(C)(C)OOC(=O)c1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3

InChI key

GJBRNHKUVLOCEB-UHFFFAOYSA-N

General description

tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane has been reported.[1]

Application

Luperox was employed as polymerization and cross-linking catalyst. It was also was employed as initiator during:
  • grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene)
  • preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition[2]

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

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This Item
16852177200124230
assay

98%

assay

98%

assay

≥95.0% (RT)

assay

98%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

solubility

water: soluble 1.18 g/L

solubility

-

solubility

-

solubility

-

density

1.021 g/mL at 25 °C (lit.)

density

0.796 g/mL at 25 °C (lit.)

density

1.021 g/mL at 25 °C (lit.)

density

1.321 g/mL at 25 °C (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

bp

109-110 °C (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

bp

50 °C/10 mmHg (lit.)

form

liquid

form

liquid

form

liquid

form

liquid


signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1

Storage Class

4.1A - Other explosive hazardous materials

wgk

WGK 2

flash_point_f

200.1 °F - closed cup

flash_point_c

93.4 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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