139459
Methyl crotonate
98%
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
| Size/SKU | Availability | Price |
|---|---|---|
5 mL | Check Cart for Availability | $34.80 |
100 mL | Check Cart for Availability | $93.90 |
500 mL | Check Cart for Availability | $142.00 |
About This Item
Linear Formula:
CH3CH=CHCOOCH3
CAS Number:
Molecular Weight:
100.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-793-7
Beilstein/REAXYS Number:
1720292
MDL number:
Assay:
98%
Form:
liquid
$34.80
Check Cart for Availability
Subscriptions are currently unavailable.
Ships Every 4 weeks
Quality Segment
assay
98%
form
liquid
refractive index
n
bp
118-120 °C (lit.)
density
0.944 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
COC(=O)\C=C\C
InChI
1S/C5H8O2/c1-3-4-5(6)7-2/h3-4H,1-2H3/b4-3+
InChI key
MCVVUJPXSBQTRZ-ONEGZZNKSA-N
General description
Methyl crotonate undergoes vinylogous aldol reaction with enolizable aldehydes in the presence of aluminum tris(2,6-di-2-naphthylphenoxide)[1].
Application
Methyl crotonate was used to investigate chemoselectivity in the reaction between methyl crotonate and benzylamine catalyzed by lipase B from Candida antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2)[2].
1 of 1
This Item | |||
|---|---|---|---|
| description 98% | description natural, ≥97%, FG | description for synthesis | description ≥96%, FG |
| assay 98% | assay ≥97% | assay ≥98.0% (GC) | assay ≥96% |
| Quality Level 100 | Quality Level 300 | Quality Level 200 | Quality Level 300, 400 |
| form liquid | form - | form liquid | form - |
| bp 118-120 °C (lit.) | bp - | bp 138-140 °C/1013 hPa | bp - |
| refractive index n | refractive index n | refractive index - | refractive index - |
| density 0.944 g/mL at 25 °C (lit.) | density - | density 0.92 g/cm3 at 20 °C | density - |
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.