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132101

Sodium trifluoroacetate

98%

Synonym(s):

Trifluoroacetic acid sodium salt

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Size/SKUAvailabilityPrice
25 g
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$45.10
100 g
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$140.00

About This Item

Linear Formula:
CF3COONa
CAS Number:
Molecular Weight:
136.01
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-879-6
Beilstein/REAXYS Number:
3597949
MDL number:
Assay:
98%
Form:
powder

$45.10


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Quality Segment

assay

98%

form

powder

mp

205-207 °C (dec.) (lit.)

density

1.49 g/mL (lit.)

functional group

fluoro

SMILES string

[Na+].[O-]C(=O)C(F)(F)F

InChI

1S/C2HF3O2.Na/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1

InChI key

UYCAUPASBSROMS-UHFFFAOYSA-M

General description

Sodium trifluoroacetate is a trifluoromethylating agent for compounds like aromatic halides, aldehydes and ketones.

Application

Sodium trifluoroacetate can be used:
  • As a trifluoromethylating agent in nucleophilic trifluoromethylation of aldehydes using copper(I) halide catalyst.
  • As a difluorocarbene precursor in gem-difluorocyclopropanation of different alkenes using azobisisobutyronitrile (AIBN) as a catalyst.
  • In the synthesis of trifluoromethylthio-substituted aromatic compounds via copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids in the presence of elemental sulfur.


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1615138483869441090
description

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description

United States Pharmacopeia (USP) Reference Standard

description

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form

powder

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form

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form

powder

assay

98%

assay

-

assay

97%

assay

98%

Quality Level

100

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Quality Level

200

density

1.49 g/mL (lit.)

density

1.49 g/mL (lit.)

density

-

density

-

mp

205-207 °C (dec.) (lit.)

mp

205-207 °C (dec.) (lit.)

mp

162-164 °C (lit.)

mp

102-104 °C (dec.) (lit.)

functional group

fluoro

functional group

-

functional group

fluoro

functional group

-


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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Codes

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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