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110124

Sigma-Aldrich

1,2,3-Trichloropropane

99%

Synonym(s):

Glycerol trichlorohydrin, Trichlorohydrin

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About This Item

Linear Formula:
CH2ClCHClCH2Cl
CAS Number:
96-18-4
Molecular Weight:
147.43
Beilstein/REAXYS Number:
1732068
EC Number:
202-486-1
MDL number:
MFCD00000946
UNSPSC Code:
12352100
eCl@ss:
39050132
PubChem Substance ID:
24846961
NACRES:
NA.22

assay

99%

form

liquid

refractive index

n20/D 1.484 (lit.)

bp

156 °C (lit.)

mp

−14 °C (lit.)

density

1.387 g/mL at 25 °C (lit.)

SMILES string

ClCC(Cl)CCl

InChI

1S/C3H5Cl3/c4-1-3(6)2-5/h3H,1-2H2

InChI key

CFXQEHVMCRXUSD-UHFFFAOYSA-N

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General description

1,2,3-Trichloropropane is reductively dehalogenated by the anaerobic bacterial strain within chloroflexi.

Application

1,2,3-trichloropropane has been used to study its reaction with OH regarding it spotential atmospheric relevance.

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - STOT RE 1 Inhalation

target_organs

Kidney,Liver,Mucous membranes

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Rate constants for the reactions of OH with chlorinated propanes.
Yujing M and Mellouki A.
Physical Chemistry Chemical Physics, 3(13), 2614-2617 (2001)
Ghufrana Samin et al.
Environmental science and pollution research international, 19(8), 3067-3078 (2012-08-10)
1,2,3-Trichloropropane (TCP) is a persistent groundwater pollutant and a suspected human carcinogen. It is also is an industrial chemical waste that has been formed in large amounts during epichlorohydrin manufacture. In view of the spread of TCP via groundwater and
Eakalak Khan et al.
Journal of hazardous materials, 161(2-3), 1024-1034 (2008-05-27)
The mineralization and biodegradability increase and their combination of two traditional and two relatively new organic contaminants by Fenton reagents with three different types of iron, Fe(2+), Fe(3+), and Fe(0) were investigated. The traditional contaminants examined were trichloroethene (TCE) and
Vaishnavi Sarathy et al.
Environmental science & technology, 44(2), 787-793 (2009-12-17)
1,2,3-Trichloropropane (TCP) is an emerging contaminant because of increased recognition of its occurrence in groundwater, potential carcinogenicity, and resistance to natural attenuation. The physical and chemical properties of TCP make it difficult to remediate, with all conventional options being relatively
Alexandra J Salter-Blanc et al.
Environmental science & technology, 45(9), 4073-4079 (2011-04-14)
The reactivity of zerovalent zinc (ZVZ) toward 1,2,3-trichloropropane (TCP) was evaluated under a variety of solution conditions, including deionized water, groundwater, and artificial groundwater, over a pH range of about 6.5-12. In deionized water, first-order rate constants for TCP disappearance
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