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233269

Sigma-Aldrich

2,4-Difluorophenol

99%

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About This Item

Linear Formula:
F2C6H3OH
CAS Number:
367-27-1
Molecular Weight:
130.09
EC Number:
206-688-0
MDL number:
MFCD00009715
UNSPSC Code:
12352100
PubChem Substance ID:
24853964
NACRES:
NA.22

Assay

99%

form

solid

refractive index

n20/D 1.486 (lit.)

bp

52-53 °C/19 mmHg (lit.)

mp

22.4 °C (lit.)

density

1.362 g/mL at 25 °C (lit.)

SMILES string

Oc1ccc(F)cc1F

InChI

1S/C6H4F2O/c7-4-1-2-6(9)5(8)3-4/h1-3,9H

InChI key

NVWVWEWVLBKPSM-UHFFFAOYSA-N

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Application

2,4-Difluorophenol has been used:
  • as starting reagent during the synthesis of 4,6-difluoro-5,7-dihydroxytryptamine
  • in the synthesis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific Blue), fluorinated fluorescent dye

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

134.6 °F - closed cup

Flash Point(C)

57 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Genetically determined differences in noradrenergic input to the brain cortex: a histochemical and biochemical study in two inbred strains of mice.
B Berger et al.
Neuroscience, 4(7), 877-888 (1979-01-01)
W C Sun et al.
Bioorganic & medicinal chemistry letters, 8(22), 3107-3110 (1999-01-05)
Two new fluorinated fluorescent dyes, 6,8-difluoro-7-hydroxy-4-methylcoumarin (Marina Blue) and 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific Blue), exhibit excellent photophysical properties among a series of novel fluorinated 7-hydroxycoumarins. Most of these fluorinated coumarins have quantum yields (0.63 to 0.89) equal to or higher than that

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