- One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst.
One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst.
Chemical communications (Cambridge, England) (2013-11-26)
Paula Rubio-Marqués, Juan Carlos Hernández-Garrido, Antonio Leyva-Pérez, Avelino Corma
PMID24270690
ABSTRACT
Cyclohexanone oxime is formed from nitrobenzene with 97% yield in a one-pot reaction catalysed by palladium and gold nanoparticles on carbon. The reaction is carried out under hydrogen at 60 °C and the overall transformation involves a multi-step catalysed mechanism from which intermediates and catalytically active species have been identified.
MATERIALS