sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

203904

Sigma-Aldrich

Nickel, powder, <150 μm, 99.99% trace metals basis

221678

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2800, slurry, in H₂O, active catalyst

510033

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2400, slurry, in H₂O, active catalyst

510068

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 3202, slurry, in H₂O, active catalyst

510041

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 4200, slurry, in H₂O, active catalyst

268283

Sigma-Aldrich

Nickel, powder, <1 μm, 99.8% trace metals basis

267058

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.99% trace metals basis

267007

Sigma-Aldrich

Nickel, foil, thickness 0.25 mm, 99.995% trace metals basis

268259

Sigma-Aldrich

Nickel, foil, thickness 0.125 mm, ≥99.9%

357634

Sigma-Aldrich

Nickel, wire, diam. 0.25 mm, ≥99.9%

GF91050140

Nickel, wire reel, 100m, diameter 0.125mm, hard, 99.98%

GF01408711

Nickel, foil, 2m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF57196569

Nickel, wire reel, 100m, diameter 0.25mm, annealed, 99%

GF58401660

Nickel, wire reel, 0.1m, diameter 1.0mm, as drawn, 99.99+%

GF86067210

Nickel, wire reel, 100m, diameter 1.0mm, as drawn, 99%

GF70540556

Nickel, tube, 500mm, outside diameter 4.5mm, inside diameter 3.154mm, wall thickness 0.673mm, hard, 99.5%

GF83472329

Nickel, wire reel, 10m, diameter 0.05mm, as drawn, 99.99+%

GF02040837

Nickel, wire reel, 100m, diameter 0.15mm, as drawn, 99%

GF04087076

Nickel, wire reel, 10m, diameter 0.25mm, as drawn, 99%

GF86231729

Nickel, foil, 4mm disks, thickness 0.05mm, as rolled, 99.99+%

GF60595061

Nickel, wire reel, 100m, diameter 0.25mm, as drawn, 99%

GF27664836

Nickel, foil, 4mm disks, thickness 0.008mm, 99.95%

GF19621144

Nickel, foil, 0.5m coil, thickness 0.25mm, annealed, 99%

GF70648915

Nickel, foil, 2m coil, thickness 0.1mm, annealed, 99%

GF41511293

Nickel, foil, 4mm disks, thickness 0.025mm, as rolled, 99.99+%

GF97678995

Nickel, wire reel, 10m, diameter 0.25mm, as drawn, 99.99+%

GF46466860

Nickel, foil, 10mm disks, thickness 0.01mm, 99.95%

GF08816711

Nickel, foil, 10m coil, thickness 0.125mm, coil width 1mm, as rolled, 99%

GF65465477

Nickel, foil, 4mm disks, thickness 0.0125mm, annealed, 99%

GF60742548

Nickel, foil, 2m coil, thickness 0.20mm, annealed, 99%