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681792

Sigma-Aldrich

N-tert-Butylbenzenesulfenamide

97%

Synonym(s):

2-Methyl-N-(phenylthio)propan-2-amine, N-(1,1-Dimethylethyl)benzenesulfenamide

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About This Item

Empirical Formula (Hill Notation):
C10H15NS
CAS Number:
19117-31-8
Molecular Weight:
181.30
MDL number:
MFCD03844776
UNSPSC Code:
12352002
PubChem Substance ID:
24885655
NACRES:
NA.22

Assay

97%

reaction suitability

reagent type: oxidant

refractive index

n20/D 1.5457

bp

57-60 °C/0.3 mmHg

density

0.997 g/mL at 25 °C

SMILES string

CC(C)(C)NSc1ccccc1

InChI

1S/C10H15NS/c1-10(2,3)11-12-9-7-5-4-6-8-9/h4-8,11H,1-3H3

InChI key

AAQBFMPKCDTAJD-UHFFFAOYSA-N

Application

Reactant for:
  • Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes
  • Anodic oxidation reactions
In the presence of NCS, this sulfenamide catalyzes the mild and selective oxidation of primary and secondary alcohols to the respective aldehydes and ketones.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

205.0 °F - closed cup

Flash Point(C)

96.11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Teruaki Mukaiyama
Angewandte Chemie (International ed. in English), 43(42), 5590-5614 (2004-10-08)
This Review describes the basic concepts that have guided our exploration of new chemical reactions by giving examples of results from my research group. Our strategy of carrying out research is to investigate three to four different topics at a

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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