- Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin.
Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin.
Chemical communications (Cambridge, England) (2011-05-05)
Barry C Pemberton, Raushan K Singh, Alexander C Johnson, Steffen Jockusch, José P Da Silva, Angel Ugrinov, Nicholas J Turro, D K Srivastava, J Sivaguru
PMID21541417
RÉSUMÉ
Guest induced shape change of the cucurbit[8]uril cavity is likely rate limiting in the supramolecular photocatalytic cycle for CB8 mediated photodimerization of 6-methylcoumarin.