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Novel carbonyl allylation mediated by SnCl2/TiCl3 in water.

Organic letters (2003-05-24)
Xiang-Hui Tan, Bo Shen, Wei Deng, Hui Zhao, Lei Liu, Qing-Xiang Guo
PMID12762664
ABSTRACT

[reaction: see text] Under the Lewis acid catalysis offered by TiCl(3), SnCl(2) can efficiently mediate the aqueous Barbier reactions between aldehydes and allyl chloride or bromide.

MATERIALS
Product Number
Brand
Product Description
474762
Sigma-Aldrich
Tin(II) chloride dihydrate, ≥99.97% trace metals basis
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