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Merck

Ruthenium-catalyzed atom transfer radical addition reactions.

Chimia (2012-08-09)
Kay Severin
ABSTRACT

Certain ruthenium complexes are potent catalysts for atom transfer radical addition (ATRA) and cyclization (ATRC) reactions, in particular if they are used in conjunction with reducing agents such as magnesium. This short overview summarizes recent developments in this area with special focus on contributions from our laboratory.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Ruthenium black
Sigma-Aldrich
Ruthenium, powder, −200 mesh, 99.9% trace metals basis
Sigma-Aldrich
Ruthenium, powder
Sigma-Aldrich
Ruthenium, sponge, −100 mesh, 99.9% trace metals basis