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Pd-catalyzed synthesis of allylic silanes from allylic ethers.

Organic letters (2009-12-03)
Ralph Moser, Takashi Nishikata, Bruce H Lipshutz
ABSTRACT

Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Allyl phenyl ether, 99%